Chemical Storage Facility Chemical Compatibility Guide

 
Chemical Incompatible With
Acetic acid Chromic acid, nitric acid, hydroxyl compounds, ethylene glycol, perchloric acid, peroxides, permanganates
Acetylene Chlorine, bromine, copper, fluorine, silver, mercury 
Acetone Concentrated nitric and sulfuric acid mixtures
Alkali and alkaline earth metals (such as powdered aluminum or magnesium, calcium, lithium, sodium, potassium) Water, carbon tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens 
Ammonia (anhydrous) Mercury (in manometers, for example), chlorine, calcium hypochlorite, iodine, bromine, hydrofluoric acid (anhydrous) 
Ammonium nitrate Acids, powdered metals, flammable liquids, chlorates, nitrites, sulfur, finely divided organic combustible materials 
Aniline  Nitric acid, hydrogen peroxide
Arsenical materials Any reducing agent 
Azides Acids
Bromine See chlorine
Calcium oxide Water
Carbon (activated) Calcium hypochlorite, all oxidizing agents
Carbon tetrachloride Sodium 
Chlorates Ammonium salts, acids, powdered metals, sulfur, finely divided organic or combustible materials 
Chromic acid and chromium trioxide  Acetic acid, naphthalene, camphor, glycerol, alcohol, flammable liquids in general 
Chlorine  Ammonia, acetylene, butadiene, butane, methane, propane (or other petroleum gases), hydrogen, sodium carbide, benzene, finely divided metals, turpentine 
Chlorine dioxide  Ammonia, methane, phosphine, hydrogen sulfide 
Copper  Acetylene, hydrogen peroxide 
Cumene hydroperoxide  Acids (organic or inorganic) 
Cyanides  Acids 
Flammable liquids  Ammonium nitrate, chromic acid, hydrogen peroxide, nitric acid, sodium peroxide, halogens
Fluorine  All other chemicals 
Hydrocarbons (such as butane, propane, benzene) Fluorine, chlorine , bromine, chromic acid, sodium peroxide
Hydrocyanic acid  Nitric acid, alkali 
Hydrofluoric acid (anhydrous)  Ammonia (aqueous or anhydrous) 
Hydrogen peroxide  Copper, chromium, iron, most metals or their salts, alcohols, acetone, organic materials, aniline, nitromethane, combustible materials 
Hydrogen sulfide  Fuming nitric acid, oxidizing gases 
Hypochlorites  Acids, activated carbon 
Iodine  Acetylene, ammonia (aqueous or anhydrous), hydrogen 
Mercury  Acetylene, fulminic acid, ammonia 
Nitrates  Sulfuric acid 
Nitric acid (Concentrated) Acetic acid, aniline, chromic acid, hydrocyanic acid, hydrogen sulfide, flammable liquids, flammable gases, copper, brass, any heavy metals 
Nitrites  Acids 
Nitroparaffins  Inorganic bases, amines 
Oxalic acid  Silver, mercury 
Oxygen  Oils, grease, hydrogen; flammable liquids, solids or gases 
Perchloric acid  Acetic anhydride, bismuth and its alloys, alcohol, paper, wood, grease, oils 
Peroxides, organic  Acids (organic or mineral), avoid friction, store cold 
Phosphorus (white)  Air, oxygen, alkalis, reducing agents
Potassium  Carbon tetrachloride, carbon dioxide, water 
Potassium chlorate  Sulfuric and other acids 
Potassium Permanganate Glycerol, ethylene glycol, benzaldehyde, sulfuric acid
Potassium Permanganate Glycerol, ethylene glycol, benzaldehyde, sulfuric acid
Selenides Reducing agents
Silver Acetylene, oxalic acid, tartaric acid, ammonium compounds, fulminic acid
Sodium Carbon tetrachloride, carbon dioxide, water 
Sodium nitrite Ammonium nitrate and other ammonium salts 
Sodium peroxide Ethyl or methyl alcohol, glacial acetic acid, acetic anhydride, benzaldehyde, carbon disulfide, glycerin, ethylene glycol, ethyl acetate, methyl acetate, furfural 
Sulfides  Acids
Sulfuric acid Potassium chlorate, potassium perchlorate, potassium permanganate (similar compounds of light metals, such as sodium, lithium) 
Tellurides Reducing agents